Structure and catalytic function of Re-oxo species grafted onto H-MFI zeolite by sublimation of Re2O7.
نویسندگان
چکیده
Isolated Re-oxo species within spatially constrained MFI zeolite channels were synthesized via exchange with Re2O7 vapor and shown to exist as isolated Re-oxo monomers. Turnover rates and Re-oxo structures did not depend on Re content. These materials were thermally stable and catalyzed alcohol oxidation reactions at unprecedented rates and near ambient temperatures.
منابع مشابه
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 128 47 شماره
صفحات -
تاریخ انتشار 2006